According to me :)
Elena Gilbert & Damon Salvatore: The Vampire Diaries
So.. They’re not exactly together yet. But they should be! Basically, Elena is dating Stefan, Damon’s brother. But, I’m going to be honest here, Stefan kind of bores me. I mean he’s nice and all, but Damon and Elena just seem right together. They have the most amazing chemistry, and I don’t understand why they aren’t together! In the season one finale, they kiss, and it is so much more real than any time that Elena and Stefan are with each other. I think they are definitely a couple that makes you want more; draws you into the show and to them. I really hope this goes somewhere.
Olivia Benson & Elliot Stabler: Law And Order: Special Victims Unit
They’re not exactly dating either, but they’ve been doing the dance for 11 years. Elliot Stabler and Olivia Benson play two detectives in the heart of the crime scene of New York, in the Special Victims Unit. They have been partners for years, and are the two focal points of the show. Although Elliot has a wife (separated, for a time) and Olivia has had boyfriends, the chemistry between them is undeniable. Not putting them together on the show would be a huge mistake.
Steven Hyde & Jackie Burkhart: That ’70s Show
Throughout the entirety of the show, I always felt that they were the best matched couple! I thought they should have ended up together at the end for sure. They are characters that you wouldn’t think would go together, but they worked perfectly!